noc20-me92-lec03_ Smart Materials-II

IIT Kanpur July 201
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Dec 2, 2023
Smart Materials-IIThis lecture introduces the concept of Magnetostrictive materials, its actuation and sensing effects along with its application in robotics. Shape memory alloys Activity questions: 1. What is Magnetostriction? 2. What does Terfenol-D stands for? 3. What d
Good morning students, welcome to the class of Foundations of Cognitive Robotics. In the
last class, we have talked about one of the basic building block for organismoid robots
which is piezoelectric smart material. We have discussed how this piezoelectric smart
material with the help of the direct and the reverse effects, we can build up different
types of actuators and sensors which can be very effective in terms of developing some
of the parts of these robots. Now, there are certain disadvantages of this piezoelectric
materials. One of course, is that it needs slightly high voltage and secondly, it is
basically a kind of a capacitor in nature. So, just like a capacitor gets discharged
with respect to time, similarly piezoelectric material loses its efficiency because it gets
discharged and hence it needs to be repoled after certain durations of time.
So, it can be used for very sophisticated type of actions, let us say for the finger
manipulations or for certain motions or rotations, but for more robust and rugged action, we
need more powerful actuators. Now, one of the most powerful actuators is magnetostrictive
actuator, we will discuss about it today. Also, we will talk about some of the artificial
muscles that we can develop with the help of another smart material called shape memory
alloy. So, let us have a look into both of these different, these two different types
of smart materials, the magnetostrictive materials and the shape memory alloy.
We will first talk about the magnetostrictive materials and the name itself is somewhat
suggesting you that these are materials which has a magnetic connection. Yes, indeed that
these are materials which responds to the change in magnetic field. So, whenever and
the advantage of the magnetic field is that you can essentially generate the changes
without physically in touch with the object, which means you can develop the force at a
distance, because magnetic field can get transferred without a physical contact. So, that
is the attractive part of it and the second part, the restrictive part in magnetostrictive
materials, it essentially refers to that the magnetostrictive material can respond to the
change in the magnetic field. So, that is what is the restriction refers to.
Now, if we look into the availability of magnetostrictive materials, we will see that
one of the most popular magnetostrictive material is terphenol D, which is made of
rare earth material called terbium and iron that is the Fe and it is first developed in
Naval Ordnance Laboratories. So, that is why their name goes and of course, there is a D
which stands for dysprosium. So, essentially it is a kind of an alloy of terbium, iron and
dysprosium. Now, what it imparts this alloy is a very high energy density. If you can look at
this video of a terphenol D material sample here and you can see that if it is hit,
you know just impact force, so much of energy gets dissipated from the system. So, it has a
very high energy density. Now, naturally this actually tells us that it will be very good in
terms of an actuator. Now, how does this magnetostriction happens in this kind of
materials? Well, you can think of that as if each of this magnetostrictive element will be
having millions of this type of small magnetic domains just like beads with its own you know
dipole direction with its own magnetic field directions which can be random to begin with.
So, that is what is the general state of a magnetostrictive material when the magnetic
field applied is 0. Now, the moment from a distance I apply a magnetic field, these each
one of these magnetic domains they start to align themselves towards the magnetic field and you can
see as a result the entire group of materials they actually expand in one direction creating
magnetostriction in the system. So, thus by applying magnetic field you can actually expand
and you can essentially only expand but by playing certain tricks you can also make it contract and
thus you can make a forward and backward movement with the help of magnetic field by using this type
of a system. Now, there are a whole lot of materials ferromagnetic materials mostly which
shows this behavior and it is initially it was observed of course in iron and nickel by Joule
long before in 1880 or so. But today the material as I already told you we use one of them is
terbium, dysprosium and iron and also there is another material in which instead of terbium
we use actually gallium. So, these materials have large magnetostriction that means you know they
show large deformation in comparison to let us say iron or nickel. So, something like 2400 parts
per million that is the level of strain that you will see. Now, this is of course a dimensionless
quantity and the other important thing is that it will show these two up to a very high temperature
which is good which means they can really work in a very rugged environment.
Now, how much is this 2400 or 2500 parts per million? It is even though you know it
looks like a large number but in terms of actual change of length it is not that large. In fact,
if you look at this curve that we have here the length of terfenol D rod let us say we
consider a 100 millimeter length rod then with about 2500 parts per million the change will
happen is only 0.24 millimeter. So, which is even smaller than 1 millimeter it may not be
visible in the naked eye but it has actually lot of power and you can also amplify just like for
piezoelectric material and then you know you can make good use of this kind of a system.
So, the other important thing for the terfenol D material is as I told you that if I change the
direction of magnetic field no matter positive or negative you will always get expansion out
of it, it always increases. But there are two interesting things to note here that if you can
somehow keep its stress to begin with you apply some initial stress you can get actually larger
strain out of the system and the second thing is that this is how you can get a bidirectional
movement let us say if you keep it already under a biased magnetic field let us say
somewhere here then if you increase the magnetic field it is going to expand,
if you decrease it is going to come down so which means you can actually get a
bidirectional movement out of the whole thing. The only thing that you are sacrificing is that
the range of strain in the earlier case if it is only unidirectional is quite large whereas
here it will be with respect to the bias and hence that range will be smaller it will be
about half of what you can get otherwise. So, this is what is the famous butterfly
curve that one has to keep in mind for designing systems using terfenol D.
Now, the attraction of such terfenol D materials are many fold for example you can use it for
large force generation up to 50 megapascal stress level you can create, you can create
large deflection up to 200 millimeter and you can get a large energy conversion efficiency
and most importantly it does not decay with time that is a very good advantage of the
magnetostrictive transducer and it is cost effective in terms of a low frequency band
it is not as high as a frequency band like a piezoelectric material and firstly it was
used in deep sea underwater applications like this Talon you can see tactical acoustic
littoral ocean network the entire sonar system of Talon is made out of magnetostrictive terfenol
D materials which is sourced by Etrema products. Now, I told you about direct and reverse effects
if you remember the direct effect is useful as a sensor when you are applying force you
can get the voltage or in this case a change of magnetization in the magnetostrictive material
that is the direct effect and the reverse effect is used for the development of actuators where
in this case as we will be changing the magnetic field we will be able to see the change in terms
of the length of the system. Now, for magnetostrictive material there are many
different effects you need not only always see the change in length you can actually generate
the change in terms of twisting in the system or a change in terms of the bulk volume in the system
and similarly the same material can respond to if there is a twisting happening or if there is a
bulk change of volume that is happening it can actually respond to that through the change with
respect to the change in magnetization. So, there are various effects of the
magnetostrictive material. Some of the magnetostrictive effects which is used for
actuation and sensing are for the reverse effect Joule effect is of course there where there is a
change in dimension but also sometimes we use the Weidmann effect where a helical magnetic field
will create a torque so that if you have a torque like you know motion generation system required
you can use the Weidmann effect and also in some other cases you can use the magneto volume effect
so that the magnetic field can create a change in volume and from the sensor perspective there
is Villary effect which actually responds to the change of stress and the axial direction and that
is reflected in terms of change in magnetostriction but there is also Matthews effect where if there
is a torque it senses and it change you know sense it in terms of a kind of a magnetic field induced
EMF and there is something which is known as Nagoka Honda effect where if there is a change
in volume it actually senses it in terms of a change in magnetic state.
So, there are three varieties of reverse effects and three varieties of direct effect which you
can use for building up actuators and sensors using magnetostrictive material. Now the
constitutive equation of such materials are actually very similar to the piezoelectric
material as you can see that for the actuators point of view we generally use the Joule effect
and in the Joule effect if you apply the magnetic field through H you will be able to see the
strain and that is the deformation and that is the deformation that we can use in terms of either by
restricting it so that you get a force or by change of length of the system.
Remember if there is a change of stress then also deformation occurs but that is not like
a smart material like behavior because that happens for any system. For the
magnetostrictive material this actually happens because of once again the coupling
called magneto mechanical coupling here like piezoelectric coupling. So, here this D actually
creates a coupling between H and epsilon so that if there is a change in H you get a change in
epsilon. Now that is as far as the actuator building is concerned. Similarly, for the
Villari effect if there is a change in stress sigma then there will be a change in magnetization
which can be sensed in terms of a change of voltage in a pickup coil etc.
And once again the magneto mechanical constant D plays an important role here because as the
D increases for a material with a smaller change of stress you will be able to get a
large change of magnetization. Of course, the magnetization can be changed by the
magnetic field also but that is something which happens for regular solenoid and it
is governed by the permeability and that is not what we are focusing for a smart material.
It is this D sigma part which we will be capitalizing for the development of the
sensors for the magnetostrictive material. Now there are many applications of it. For
example, if you want to control the noise and vibration let us say during the motion
of a robot this is used. Machine tools if you have controlling of machine tools,
controlling of servo valves just like I told you that so many servo valves are required for say
for example the different types of pneumatic actuation. So, you can actually use these
magnetostrictive material instead of you know compressor based pneumatic materials.
It will be much less bulky. So, for servo valves you can use it. You can use it for
hybrid motors, for sonar devices, for brake systems, micropositioner and different types
of cleaning and welding type of applications. Now one of the very common magnetostrictive
actuator is called magnetostrictive mini actuator. So, if you look at this magnetostrictive mini
actuator in this case you can see that there is a terfinal D rod which is sitting inside as you
can see it here and then there are this magnetization coils and there is a set of
permanent magnet. So, what will happen is that the moment I will apply and because of this
permanent magnet it is already biased. Now the moment I will apply an external magnetic field
then depending on the direction of it this terfinal D rod will expand or contract and
as a result this piston will move forward and backward and that can be used in terms
of motion generation in a robot for various types of applications.
Now here I will show you a very interesting application of magnetostrictive material and
this is in terms of its motion as an earthworm in a conduit. So, you can see this is also known
as inchworm motion and there are you know inside this there are this magnetostrictive materials
and there is a stick slip happening and because of the expansion and contractions and you can
see that you know that that is happening and that is creating the stick slips and the whole
thing is actually propagating. So, you can make it wired or wireless but this has excellent
applications in terms of development of pipe health monitoring robots and you see this is
an application which is completely wireless and you see the whole thing is moving vertically.
So, if you want to let us say create an animalistic motion let us say a kind of
a ant like motion we can actually miniaturize it as you can see here that people have even
miniaturized such a thing. So, a ant like motion and inside a conduit this particular type of
robot using magnetostrictive actuator can be very good in terms of generation of such motions and
you can see that how small you can make the whole thing and here you can see that how nicely it is
going inside a pipe and if you have sensors it can actually monitor in that case the nature
of changes that is happening in the pipe and it can do that both upward and downward.
So, you can have a versatile movement that you can generate out of this system. So,
this is what is about the magnetostrictive material. I told you that we will be discussing
two materials today. One is the magnetostrictive material and for which I have shown you that
their greatest application for our purpose will be in terms of generating locomotions
and that you can do for different very complex environments you can do it. Of course,
you can use such materials for sensors as well, but mostly it is used as actuators.
Other than these two, there is also a third way of creating motions which we will discuss today
and that is with the use of certain artificial muscles. Now, one of the artificial muscle
category is actually metallic alloys and it is known as popularly shape memory alloy. So,
let us have a look into how this shape memory alloys behave, how we can actually use them in
terms of actuations and in some cases as sensors as well. Let us look into the
nitty-gritties of shape memory material. So, we will look into the smart materials
based on shape memory alloys and electroactive polymer and today we will specifically focus on
shape memory alloys. Now, what is a shape memory effect? It is some kind of a memory,
and it is a memory as the name suggests is related to shape. So, precisely this material
has a memory in its parent stage which is called austenite stage which happens at a
high temperature phase. So, generally what we do is that we cool this material, so it
comes to a low temperature phase or a martensite phase, then you carry out all the deformations
and then whenever you will be heating it, it will go back to its memorized shape at the austenite
phase. So, that memory is called a shape memory effect. Now, in some cases, it can memorize both
the austenite and martensite stage if you properly train it. So, this case it is called one-way shape
memory effect, whereas if you can properly train it so that both the phases it can memorize its
shape, it is called two-way shape memory effect. So, you can develop both the type of such shape
memory effects. Now, the materials which show such a memory effect, it was first observed that in
1932 in gold cadmium alloy. Later on, it was found that there are other alloys like ternary
alloys of copper, zinc and aluminum or copper, aluminum and nickel or the best one is called
nickel-titanium. In fact, again Nabar Ordnance Laboratory discovered it, so their name goes
with the whole thing and it is popularly known as nitinol today. So, it is a particular ratio
of about 45 to 55 percent of nickel and titanium which actually make this nitinol material and
it shows a very large shape memory effect. Now, as I told you that this shape memory
material has actually two different types of structures. In the austenite phase, it has a
body centered cubic structures, you can see the atoms at the corners and at the center of the
body, whereas at the low temperature phase, it has a face centered cubic structure. You can see
that instead of just at the center of the body, there are these atoms which nicely comes into
the center of the phases. Now, something if it is inside the center of the body actually
inherently makes it harder and if it is a FCC, inherently the face centered cube is
actually more flexible structure. The other thing to note is that at the BCC,
in the austenite phase, these crystal structures of SMA is essentially cubic in nature. So,
all the lattices are equally dimensioned, whereas in this case, in the martensite phase,
it becomes tetragonal structure. So, where you can see that the sizes are not the same,
I mean it would be different essentially. Essentially, this direction it will be
different in comparison to the other two directions. So, this is what is the crystal
structure of SMA and why we go for SMA is that you get a large actuation stress, say for example,
something like 0.1 meganewton meter per kg in comparison to PZT, it gets about you can see
here that 100 to 1000 times in fact more you can get you know I mean some in between you can get
for the SMAs and also in comparison to human muscle also you can get a very high amplification,
not as high as PZT, but still it is quite high. So, once again you know you are coming up to 0.5
here. So, it is slightly less than 100 times that you are getting through this.
The strain is also very high. So, essentially you are getting a large stress and strain out
of the system and that is what is very lucrative and you can get this material both in wire form
as well as in a spring form. Spring forms give a better actually stress and deformation,
but the only catch is that the spring form is actually more complex to analyze. So,
modeling is little bit difficult in the spring form.
Now, if you look at this diagram very carefully, it actually describes the entire process. As you
can see here that in this case you know we have the stress, three axis, strain and temperature.
So, let us say the material is for starting from this level when everything is 0. Now, if I apply
the stress and to begin with let us say that it is at austenite phase. If I apply the stress,
it will deform until beyond a point it will behave almost like a plastic deformation and then if I
reduce the stress this plastic deformation will get you know reversed ok. So, this can happen
inside the austenite phase, but if you cool this material let us say you are in the martensite
phase. Then if I increase the stress, it will then go to the plastic deformation,
it will go to detwine martensite. I will once again reduce the stress,
now it will not go back to 0 strain, it will be somewhere here and then if you heat it up
only then it will come back to its parent phase. So, that is what is the shape memory effect.
And also the hysteresis in this effect the stress based effect is also called
super elasticity. So, these are the two effects that is generally observed
in the shape memory alloy. Applications as I told you is phenomenal, it is increasing every day
mechanical, robotics, biomedical, civil structures and composite. Specifically for robotics,
it is used in mini actuator sensors, biomimetic robotic hands and crawler robots. So, there are
very many applications of the shape memory alloy today.
Now, here there are some examples as I am showing you about the SMA type of an artificial muscles
which is joined using springs, you can see it in the two views. Now, this can be used for
developing the fingers. So, those ASIMO fingers which is controlled by servo motor can be in fact
better controlled with less power with the help of SMAs if you can model it properly.
And you can actually determine the forces there so that it does not get crushed. So,
depending on the type of element you are holding you can control the force. So, that is the
beauty of the SMA actuated prosthetic hand. SMA is also used in terms of sensors. So,
there are not many applications, but we have devised some applications for SMA as sensors as
well. You can see here is a SMA based sensor where there is a rotating drum which is having the
contact end points and these two points are connected with the help of styluses and these
styluses are operated by SMA wires. Now, the moment the two styluses are on conductive tape
there is a current that will pass through and as soon as there is a current that will pass
through there is a heating effect and the switches A and B will operate so that you will get a signal
out of them. And once one of the stylus will miss during rotation it will not be able to operate
and hence you will see that the signal will come down to 0.
So, by measuring these two counter outputs you will be able to find out how much of
rotation is happening on this particular drum. Thus, you can actually make a nice sensor a
very robust sensor out of it. The details of it is again available in one of our papers
in sensors and transducers. Now, you can also use this SMS in terms of muscles let us say if there
are two compliant links. So, there are two links and I have attached them with two SMA wires and
you can see that by doing that you can actually very nicely manipulate the tip of this whole
system. So, this is a fabricated two link mechanism where SMA wire is controlling
essentially two SMA wires are controlling the two link deformation and by that it is controlling
this point of interest the topology of this point. So, that it can be used in terms of various types
of manipulations for example. So, this is once again is reported in one of our paper in journal
of mechanical design. Now, you can do very many actually different type of shapes you can generate
to it. So, here for example, you can see that there is a figure of 8 that is generated by using
the shape memory alloy based two link mechanism. In fact, one can actually find out that what kind
of current through simulation will be able to generate it and you can actually feed that same
current loop into the system like this type of a system you feed back the currents in the two
SMA wires related to the two links, link 1 and link 2 and you will be able to get the desired
deflection in the system. So, this is one way of using SMA for developing a nice manipulators
which can be used for finger movements things like that. Now, it is used in general for control
of aerodynamic surfaces like for control of motion, for vibration isolation, for grasping
of robotic fingers, space exploration as filter and for deployment of solar array hinges.
Truly you know too many applications it is increasing day by day.
What is the advantage? I am just giving here a quick comparison PZT which was a
piezoelectric material, its strain level is 1000. PVDF which is a plastic piezoelectric
material let us call it, its strain level is 700. Turphenol-D we discussed today has a strain
level of 2000 which means it gives more strain than these two. Nitinol will give you about 20,000,
it gives much more than all the three. Only thing is that in terms of elastic modulus,
this one is little bit softer whereas, this one Turphenol-D and PZT both of them are equally
high in nature. And then from the bandwidth point of view Turphenol-D is the SMA is the
smallest then Turphenol-D and followed by the piezoelectric material. So, this is just the
conglomeration of the properties so that we can take a quick decision in terms of the use of the
smart material. Now, this is where we will put an end of this lecture. In the next lecture,
we will look into another kind of a smart muscle which is made of electroactive
polymers. Shape memory alloy we have discussed today. Thank you.
