@a2zpractical991 In this video, we will learn the Postulates of Werner's Theory of Coordination Compounds in a simple and easy-to-understand way.
This lecture is specially designed for Class 12 Chemistry students preparing for the Maharashtra State Board HSC Board Examination.
📚 Topics Covered in This Video:
Introduction to Werner's Coordination Theory
Primary Valency
Secondary Valency
Difference between Primary and Secondary Valency
Ionisable and Non-ionisable Valencies
Coordination Number and Geometry
Explanation with suitable examples
Important points for HSC Board Examination
🎯 Useful For:
Class 12 Maharashtra Board Students
HSC Board Examination 2027
Coordination Compounds Chapter
Chemistry Board Exam Preparation
Conceptual Understanding and Revision
If you want to score good marks in Chemistry, make sure to watch the complete lecture.
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AI Generated·May contain errors
So, kids, today we were going to discuss Warner's theory which is
Coordination chemistry is one of the most important fields in chemistry.
People squared off against something
Something in brackets
Here in the square bracket
But you must have seen some metals
The scent in the boy's armpits and the hole of the fong.
What do you say, what do you say, clean speak, children, if
Has happened
Inside the squib, this is metal, and this is it.
It's legendary, it's real, this is the center metal, remember
After that, why do the negatively charged anions go to the cathode? This is the parrot space of the lour.
Here is the request
Get away from these bonds
The beginning of codination chemistry occurred and
Warner's had explained all of this.
Who explained this to Warner?
So, Warner is called the father of coordination chemistry.
If you don't understand this, it works something like this.
Like a cyanide, two cyanides, that's fine
Such cyanide ones that are anions, right?
No, not its electrons to the central metal
When sent into orbit, due to which there is one here
Bonding occurs between a child and this same bonding is what we people coordinate as cordination bond.
They say, and this entire explanation has been provided by our Varnar Baba.
So that's why it's called the Warner Theory.
Now pay close attention and see exactly what's in the Warner Theory
So we will examine the postulates
of Warner's theory, and we will first examine the initial postulate, which is yours
Metal is something, as I showed you, metal possesses two types.
There is one valence, a child, located exactly outside the square bracket of this.
We say primary valences, and there is one inside square brackets.
The anions inside that connect to the metal are what we call
Alright, go and check it yourself.
If you've studied coordination chemistry, that's great, alright,
These are called primary valences, and these are called secondary valences.
primary valences, no, if you,
If you dissolve this in water, it becomes ionizable.
It could come out, but the child who has secondary valences
Primary valence is the ionizable valence.
The point is, it might come out when you put it in water.
The fluorides will be removed, and the secondary valence will remain.
It's non-ionizable, okay? Remember two things.
Let's keep going; now we see the children who are our primary valences.
Isn't it so, that satisfy, meaning whatever your primary valences are
Here there are three primary valencies, okay, three of them.
Chlorite scan, tell me, child, what is this telling you?
The plus the charge plus the metal you have
It's a charge, whether it's your primary or your ionizable one.
It is consistent with the identities; the diet satisfies.
The given primary valence of the metal atom is that of
Yes, this is the primary valence, isn't it, for metals?
Satisfied, satisfied, what does it mean, like here
If you remove three chloride ions, then why copper?
Three positive charges will be applied, okay? So, whatever the uncharged...
Three there is a child in primary valencies there
Satisfy the valencies of the metal
What exactly are you doing to my metal valences?
Cutting, satisfying, this time metal paper
plus 3 charge, due to which
What is here attached to the iron with 3 chlorides?
Alright, regarding your primary valency generally
It will be, basically those are your anions themselves
It will happen, those cuts will never happen, okay
Because the more anions there are in it
A positive charge of that magnitude will appear on the copper here, just like the 3 here, right?
It's Cl3, so the copper has a +3 charge on top, right?
What are the three anayans there, given, and what is your second one,
The second one, your secondary valencies, which
What will be the coordination number of the compound, meaning copper?
What will be the coordination number here, and how much copper?
It will create a bond with people, okay? So who is this?
This shows your secondary balance, which is
if it is non-ionizable, then the same as the secondary coordination sphere consists
of entities which satisfy the
secondary valences and are non-ionizable. Okay then
This satisfies the secondary valences; now look here.
Here, the secondary valences are six NH3 molecules.
So, the coordination number here will become 6 due to this.
And the child states this same 6 coordination number.
Its geometry will be octahedral.
Which geometry will it be? It will be octahedral geometry.
And what exactly is octahedral geometry?
due to the secondary balances.Does not contain any additional information or context.
carries out and from that very moment a special arrangement
It seems you're meeting Friedricha, that's right, this one
The verse arrangement decides that this donkey is incompetent.
It's telling this prepared pular that the number is 230.
This is telling you about secondary valences.
Secondary valences are non-ionizable.
and secondary valences indicate the coordination number
of the central metal atom or ion
Because of which we decide the entire structures
It will be octahedral, it will be tetrahedral, okay
That is, the secondary balances have fixed spatial arrangements.
around the central metal atom and describe the structures
What makes structures?
So this is all about the postulates of Warner's theory
Warner didn't tell us the postulates
Warner didn't tell us that actually
Coordination compounds are such compounds
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